Newcastle University

Background

Outside of my work interests, I initiate and organise a number of chemistry related outreach and promotional activities, mainly on the behalf the Royal Society of Chemistry (RSC). I am assistant secretary and CLS representative for the Newcastle and North East Coast section of the RSC and recently joined the Northumbria branch of the British Science Association as programme co-ordinator.

The most recent successes have been a renewable energy workshop for primary school children and assisting Cumbria RSC section in starting their regional top of the bench competition.

2005, 2007 and 2009: RSC local section joint organiser of Chemistry week activities in Newcastle.

2006 and 2007: Royal Society partnership grants with St Teresa's primary school, Heaton in conjunction with Dr. Karl Jankowski, St Mary's Comprehensive.

2005-2008: Joint organiser of the buckyball challenge with Dr. Ashleigh fletcher.

2006-2008: Organiser of the RSC local School's quiz
2007-2008: Organiser of the RSC local sixth form lecture
2007-2008: Organiser of the RSC local year 6 lecture
2007- CSI style event for Year 10 at Marden Comprehensive
2008: Talk at St Stephen's careers event

2008: Organised a stand at Thomas Hepburn schools science week event.

2008: Renewable Energy workshop and hydrogen rocket launch for year 6 pupils of St Teresa's and St Stephen's primary schools, with the Sir Jospeh Swan institute. Supported by Newcastle University's Catherine Cookson fund.

2008: Organiser of inaugral North East Chemistry careers fair in association with the RSC's Chemnet.

Roles and Responsibilities

2007 and 2009: Tutor on the BCA intensive crystallography school.

2007-2010: Member of chemical crystallography group (CCG) committee of the BCA

2008: Local organiser of the Chemical Crystallography Group Autumn meeting at Newcastle

2010-present: Branch representative on British Science Association General committee

2006-present: Newcastle and North East coast RSC section Committee for local section sections representative

2008-present: Newcastle and North East coast RSC section assistant secretary

2005, 2007 and 2009: Local chemistry week organiser

2008-present: Programme coordinator for Northumbria branch of British Science Association

Qualifications

University of Bath
Oct 1994 - July 1998
2:1 BSc Honours in Chemistry with Industrial Training
Final Year Project: Molybdenum co-ordination complexes
Supervisor: Prof. B. Brisdon

University of Bath
Oct 1998 - Oct 2001
EPSRC funded PhD
Title: Hydrogen bond directed crystal engineering of metal complexes
Supervisor: Dr. A. D. Burrows and Dr. M. F. Mahon

Memberships

Royal Society of Chemistry (MRSC)

British Crystallographic Assocation (BCA)

British Science Association

Languages

Welsh

Informal Interests

Watching and playing cricket, reading, cinema, visiting historical sites and buildings.

Research Interests

Small molecule crystallography including applications of synchrotron radiation.

Synthetic research into hydrogen bonded and coordination frameworks.

Esteem Indicators

2008: Local Organiser of Chemical Crystallography Group Autumn Meeting

Invited Speaker; BCA Spring Meeting 2010

Funding

July 2007- £2500 from Chemistry:The next generation to run a CSI style event at Marden comprehnsive school.

July 2008: £720 from Newcastle University's Catherine Cookson fund for renewable energy workshop.

May 2009: Two grants of £3000 to run Royal Society Partnership Grants

Undergraduate Teaching

CHY2401 Lab organiser

SFY0005 Lecturer

Supervision of MChem stage 4 research project student.

• Davies LH, Harrington RW, Clegg W, Higham LJ. Air-Stable, Highly Fluorescent Primary Phosphanes. Angewandte Chemie 2012, (epub ahead of print).
• Kandasamy B, Wills C, McFarlane W, Clegg W, Harrington RW, Rodriguez-Fortea A, Poblet JM, Bruce PG, Errington RJ. An Alkoxido-Tin-Substituted Polyoxometalate [(MeO)SnW5O18](3-): The First Member of a New Family of Reactive {SnW5} Lindqvist-Type Anions. Chemistry: A European Journal 2012, 18(1), 59-62.
• Doherty S, Knight JG, Ellison J, Weekes D, Harrington RW, Hardacre C, Manyer H. An efficient recyclable peroxometalate-based polymer-immobilised ionic liquid phase (PIILP) catalyst for hydrogen peroxide-mediated oxidation. Green Chemistry 2012, 14(4), 925-929.
• Achard TRJ, Clegg W, Harrington RW, North M. Chiral salen ligands designed to form polymetallic complexes. Tetrahedron 2012, 68(1), 133-144.
• Bai D, Benniston AC, Hagon J, Lemmetyinen H, Tkachenko NV, Clegg W, Harrington RW. Exploring Forster electronic energy transfer in a decoupled anthracenyl-based borondipyrromethene (bodipy) dyad. Physical Chemistry Chemical Physics 2012, 14(13), 4447-4456.
• Izod K, Clark ER, Clegg W, Harrington RW. Hypervalent Sulfur-Functionalized Diphosphagermylene and Diphosphastannylene Compounds. Organometallics 2012, 31(1), 246-255.
• Benniston AC, Winstanley TPL, Lemmetyinen H, Tkachenko NV, Harrington RW, Wills C. Large Stokes Shift Fluorescent Dyes Based on a Highly Substituted Terephthalic Acid Core. Organic Letters 2012, 14(6), 1374-1377.
• Ficks A, Hiney RM, Harrington RW, Gilheany DG, Higham LJ. MOP-phosphonites: A novel ligand class for asymmetric catalysis. Dalton Transactions 2012, 41(12), 3515-3522.
• Benniston AC, Hagon J, He XY, Lemmetyinen H, Tkachenko NV, Clegg W, Harrington RW. Photoinduced charge shift and charge recombination through an alkynyl spacer for an expanded acridinium-based dyad. Physical Chemistry Chemical Physics 2012, 14(9), 3194-3199.
• Coyle L, Middleton PS, Murphy CJ, Clegg W, Harrington RW, Errington RJ. Protonolysis of [(ⁱPrO)TiMo₅O₁₈](^3-): access to a family of TiMo₅ Lindqvist type polyoxometalates. Dalton Transactions 2012, 41(3), 971-981.
• Bakri R, Booth A, Harle G, Middleton PS, Wills C, Clegg W, Harrington RW, Errington RJ. Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo₁₂O₄₀]^3– by mild, non-aqueous reductive aggregation. Chemical Communications 2012, 48(22), 2779-2781.
• Benniston AC, Hagon J, He XY, Yang SJ, Harrington RW. Spring Open Two-plus-Two Electron Storage in a Disulfide-Strapped Methyl Viologen Derivative. Organic Letters 2012, 14(2), 506-509.
• Khaledi M, Kia R, Clegg W, Harrington RW. (E,E)-N-1,N-4-Bis(2,6-difluorobenzylidene)butane-1,4-diamine. Acta Crystallographica. Section E: Structure Reports Online 2011, 67(11), O3108-U2067.
• Izod K, Wills C, Harrington RW, Clegg W. Agostically-stabilized dialkylstannylenes and plumbylenes. In: Abstracts of Papers of the American Chemical Society: 241st National Meeting of the American Chemical Society. 2011, Anaheim, California, USA: American Chemical Society.
• Choi JH, Clegg W, Harrington RW. Crystal Structure and Spectroscopic Properties of cis-beta-Diazido(1,4,7,11-tetraazaundecane)chromium(III) Bromide. Zeitschrift fuer Anorganische und Allgemeine Chemie 2011, 637(5), 562-566.
• Mercier LG, Furukawa S, Piers WE, Wakamiya A, Yamaguchi S, Parvez M, Harrington RW, Clegg W. Design, Synthesis, and Characterization of Functionalized Silepins: High Quantum Yield Blue Emitters. Organometallics 2011, 30(6), 1719-1729.
• Benniston AC, Harriman A, Yang S, Harrington RW. Highly-Strained Cyclophanes Bearing Both Photo- and Electro-Active Constituents. Tetrahedron Letters 2011, 52(41), 5315-5318.
• Hardcastle IR, Liu J, Valeur E, Watson A, Ahmed SU, Blackburn TJ, Bennaceur K, Clegg W, Drummond C, Endicott JA, Golding BT, Griffin RJ, Gruber J, Haggerty K, Harrington RW, Hutton C, Kemp S, Lu X, McDonnell JM, Newell DR, Noble ME, Payne SL, Revill CH, Riedinger C, Xu Q, Lunec J. Isoindolinone Inhibitors of the Murine Double Minute 2 (MDM2)-p53 Protein-Protein Interaction: Structure-ActivityStudies Leading to Improved Potency. Journal of Medicinal Chemistry 2011, 54(5), 1233-1243.
• Petrou AL, Koutselos AD, Wahab HS, Clegg W, Harrington RW, Henderson RA. Kinetic and Theoretical Studies on the Protonation of [Ni(2-SC₆H₄N){PhP(CH₂CH₂PPh₂)₂}]⁺: Nitrogen versus Sulfur as the Protonation Site. Inorganic Chemistry 2011, 50(3), 847-857.
• Petrou AL, Koutselos AD, Wahab HS, Clegg W, Harrington RW, Henderson RA. Kinetic and Theoretical Studies on the Protonation of [Ni(2-SC6H4N){PhP(CH2CH2PPh2)(2)}](+): Nitrogen versus Sulfur as the Protonation Site. Inorganic Chemistry 2011, 50(3), 847-857.
• Galindo MA, Hannant J, Harrington RW, Clegg W, Horrocks BR, Pike AR, Houlton A. Pyrrolyl-, 2-(2-thienyl)pyrrolyl- and 2,5-bis(2-thienyl)pyrrolyl-nucleosides: synthesis, molecular and electronic structure, and redox behaviour of C5-thymidine derivatives. Organic & Biomolecular Chemistry 2011, 9(5), 1555-1564.
• Doherty S, Knight JG, Addyman CR, Smyth CH, Ward NAB, Harrington RW. Ruthenium Complexes of k(P)- and k(P)-h⁶-Coordinated KITPHOS Monophosphines: Efficient Catalysts for the Direct Ortho Arylation of 2-Phenylpyridine and N-Phenylpyrazole with Aryl Chlorides. Organometallics 2011, 30(21), 6010-6016.
• McEntee GJ, Vilela F, Skabara PJ, Anthopoulos TD, Labram JG, Tierney S, Harrington RW, Clegg W. Self-assembly and charge transport properties of a benzobisthiazole end-capped with dihexyl thienothiophene units. Journal of Materials Chemistry 2011, 21(7), 2091-2097.
• Beheshti A, Clegg W, Fard SAM, Harrington RW, Nobakht V, Russo L. Synthesis and crystal structures of dimeric W(Mo)/Cu/S and polymeric W/Cu/S neutral clusters with flexible 1,4-bis(3,5-dimethylpyrazol-1-yl)butane as a linker ligand. Inorganica Chimica Acta 2011, 376(1), 310-316.
• Spencer J, Baltus CB, Press NJ, Harrington RW, Clegg W. Synthesis of a (piperazin-1-ylmethyl)biaryl library via microwave-mediated Suzuki-Miyaura cross-couplings. Tetrahedron Letters 2011, 52(31), 3963-3968.
• Izod K, Watson JM, Clegg W, Harrington RW. Synthesis, structures and stabilities of thioanisole-functionalised phosphido-borane complexes of the alkali metals. Dalton Transactions 2011, 40(44), 11712-11718.
• Ficks A, Martinez-Botella I, Stewart B, Harrington RW, Clegg W, Higham LJ. Taming Functionality: Easy-To-Handle Chiral Phosphiranes. Chemical Communications 2011, 47(29), 8274-8276.
• Holden DL, Goulding HV, Bacsa J, Berry NG, Greeves N, Stephenson RA, Harrington RW, Clegg W, Fogg AM. Unusual Hybrid Materials Prepared by the Oxidation of a Ketone. Crystal Growth & Design 2011, 11(7), 3013-3019.
• Clegg W, Harrington RW, North M, Villuendas P. A Bimetallic Aluminum(salen) Complex for the Synthesis of 1,3-Oxathiolane-2-thiones and 1,3-Dithiolane-2-thiones. Journal of Organic Chemistry 2010,75 18 6201-6207.
• Burke PJ, Wong LC, Clegg W, Harrington RW, Jenkins TC, Knox RJ, Meikle IT, Stanforth SP. An unexpected ring contraction of two nitroaryl pro-drugs: conversion of N-(nitroary1)-3-chloropiperidine derivatives into N-(nitroaryl)-2-chloromethylpyrrolidines. Tetrahedron Letters 2010, 51(30), 3918-3921.
• Benniston AC, Copley G, Harriman A, Howgego D, Harrington RW, Clegg W. Cofacial Boron Dipyrromethene (Bodipy) Dimers: Synthesis, Charge Delocalization, and Exciton Coupling. Journal of Organic Chemistry 2010, 75(6), 2018-2027.
• Choi JH, Clegg W, Harrington RW, Lee SH. Crystal Structure and Spectroscopic Properties of trans-Dibromobis(1,2-ethanediamine)chromium(III) Perchlorate. Journal of Chemical Crystallography 2010, 40(7), 567-571.
• Choi JH, Clegg W, Harrington RW. Crystal Structure of [2,13-Dibenzyl-5,16-dimethyl-2,6,13,17-tetraazatricyclo(14,4,0(1.18),0(7.12))docosane]copper(II) Diperchlorate. Journal of Chemical Crystallography 2010, 40(1), 80-84.
• Clegg W, Harrington RW, North M, Pasquale R. Cyclic Carbonate Synthesis Catalysed by Bimetallic Aluminium-Salen Complexes. Chemistry: A European Journal 2010, 16(23), 6828-6843.
• Clegg W, Harrington RW, North M, Pizzato F, Villuendas P. Cyclic carbonates as sustainable solvents for proline-catalysed aldol reactions. Tetrahedron: Asymmetry 2010, 21(9-10), 1262-1271.
• Doherty S, Knight JG, Smyth CS, Ward NAB, Robson KJ, Tweedly S, Harrington RW, Clegg W. Efficient Cycloisomerisation of Propargyl Amides by Electrophilic Gold(I) Complexes of KITPHOS Monophosphines: A Comparative Study. Organometallics 2010, 29(18), 4139-4147.
• Benniston AC, Harriman A, Whittle VL, Zelzer M, Harrington RW, Clegg W. Exciplex-like emission from a closely-spaced, orthogonally-sited anthracenyl-boron dipyrromethene (Bodipy) molecular dyad. Photochemical and Photobiological Sciences 2010, 9(7), 1009-1017.
• Iglesias M, Beetstra DJ, Cavell KJ, Deryisi A, Fallis IA, Kariuki B, Harrington RW, Clegg W, Horton PN, Coles SJ, Hursthouse MB. Expanded-Ring and Backbone-Functionalised N-Heterocyclic Carbenes. European Journal of Inorganic Chemistry 2010, (11), 1604-1607.
• Izod K, Stewart J, Clark ER, Clegg W, Harrington RW. Germanium(II) and Tin(II) Complexes of a Sterically Demanding Phosphanide Ligand. Inorganic Chemistry 2010, 49(10), 4698-4707.
• Izod K, Clegg W, Harrington RW. Lanthanide(II) complexes of a phosphine-borane-stabilised carbanion. Dalton Transactions 2010, 39(29), 6705-6709.
• Yang SJ, Brooks AC, Martin L, Day P, Pilkington M, Clegg W, Harrington RW, Russo L, Wallis JD. New chiral organosulfur donors related to bis(ethylenedithio)tetrathiafulvalene. Tetrahedron 2010,66 34 6977-6989.
• Doherty S, Knight JG, McGrady JP, Ferguson AM, Ward NAB, Harrington RW, Clegg W. ortho,ortho '-Substituted KITPHOS Monophosphines: Highly Efficient Ligands for Palladium-Catalyzed C-C and C-N Bond Formation. Advanced Synthesis & Catalysis 2010, 352(1), 201-211.
• Wills C, Izod K, Clegg W, Harrington RW. Oxidation reactions of a phosphine-borane-stabilised dialkylstannylene. Dalton Transactions 2010, 39(9), 2379-2384.
• Martin E, Clegg W, Harrington RW, Hughes DL, Hursthouse MB, Male L, Lancaster SJ. Pyridine and benzonitrile adducts of bis(4-nonafluorobiphenyl)zinc. Polyhedron 2010, 29(1), 405-413.
• McEntee GJ, Skabara PJ, Vilela F, Tierney S, Samuel IDW, Gambino S, Coles SJ, Hursthouse MB, Harrington RW, Clegg W. Synthesis and Electropolymerization of Hexadecyl Functionalized Bithiophene and Thieno[3,2-b]thiophene End-Capped with EDOT and EDTT Units. Chemistry of Materials 2010, 22(9), 3000-3008.
• Nicholls JL, Hulse SE, Callear SK, Tizzard GJ, Stephenson RA, Hursthouse MB, Clegg W, Harrington RW, Fogg AM. Synthesis and Structure of Pillared Molybdates and Tungstates with Framework Layers. Inorganic Chemistry 2010,49 18 8545-8551.
• Errington RJ, Coyle L, Middleton PS, Murphy CJ, Clegg W, Harrington RW. Synthesis and Structure of the Alkoxido-Titanium Pentamolybdate ((Bu4N)-Bu-II)(3)[((PrO)-Pr-i)TiMo5O18]: An Entry into Systematic TiMo5 Reactivity. Journal of Cluster Science 2010,21 3 503-514.
• Izod K, Wills C, Clegg W, Harrington RW. Synthesis, Structure, and Solution Behavior of a Phosphine-Borane-Stabilized 1,3-Dicarbanion. Organometallics 2010,29 21 4774-4777.
• Izod K, Stewart J, Clegg W, Harrington RW. Synthesis, structures and dynamic behavior of intramolecularly base-stabilized diphosphatetrylenes containing a five-membered chelate ring. Organometallics 2010, 29(1), 108-116.
• Cotterill LJ, Harrington RW, Clegg W, Hall MJ. Thermal 1,3-Trityl Migrations in Diels-Alder Domino Reactions of 1-Trityl-4-vinyl-1H-imidazoles. Journal of Organic Chemistry 2010, 75(13), 4604–4607.
• Goulding HV, Hulse SE, Clegg W, Harrington RW, Playford HY, Walton RI, Fogg AM. Yb3O(OH)(6)Cl center dot 2H(2)O: An Anion-Exchangeable Hydroxide with a Cationic Inorganic Framework Structure. Journal of the American Chemical Society 2010, 132(39), 13618-13620.
• Izod K, Wills C, Clegg W, Harrington RW. Acyclic Dialkylstannylene and -Plumbylene Compounds That Are Monomeric in the Solid State. Organometallics 2009, 28(19), 5661-5668.
• Doherty S, Smyth CH, Harriman A, Harrington RW, Clegg W. Can a Butadiene-Based Architecture Compete with its Biaryl Counterpart in Asymmetric Catalysis? Enantiopure Me-CATPHOS, a Remarkably Efficient Ligand for Asymmetric Hydrogenation. Organometallics 2009, 28(3), 888-895.
• Izod K, Stewart J, Clark ER, McFarlane W, Allen B, Clegg W, Harrington RW. Dynamic Behavior of Intramolecularly Base-Stabilized Phosphatetrylenes. Insights into the Inversion Processes of Trigonal Pyramidal Geramanium(II) and Tin(II) Centers. Organometallics 2009, 28(12), 3327-3337.
• Forgie JC, Kanibolotsky AL, Skabara PJ, Coles SJ, Hursthouse MB, Harrington RW, Clegg W. Electrochemical, Spectroelectrochemical, and Comparative Studies of Novel Organic Conjugated Monomers and Polymers Featuring the Redox-Active Unit Tetrathianaphthalene. Macromolecules 2009, 42(7), 2570-2580.
• Errington RJ, Harle G, Clegg W, Harrington RW. Extending the Lindqvist Family to Late 3d Transition Metals: A Rational Entry to CoW5 Hexametalate Chemistry. European Journal of Inorganic Chemistry 2009, (34), 5240-5246.
• Belokon YN, Clegg W, Harrington RW, Maleev VI, North M, Omedes Pujol M, Usanov DL, Young C. Mechanism-Guided Development of VO(salen)X Complexes as Catalysts for the Asymmetric Synthesis of Cyanohydrin Trimethylsilyl Ethers. Chemistry: A European Journal 2009, 15(9), 2148-2165.
• Wills C, Izod K, Young J, Clegg W, Harrington RW. Mixed donor-functionalised phosphinomethanide complexes of the alkali metals; synthesis, structures, and solution dynamics. Dalton Transactions 2009, (31), 6159-6165.
• Benniston AC, Elliott KJ, Harrington RW, Clegg W. On the Photochemical Stability of the 9-Mesityl-10-methylacridinium Cation. European Journal of Organic Chemistry 2009, (2), 253-258.
• Galindo MA, Amantia D, Martinez AM, Clegg W, Harrington RW, Martinez VM, Houlton A. Probing Metal-Ion Purine Interactions at DNA Minor-Groove Sites. Inorganic Chemistry 2009, 48(21), 10295-10303.
• Galindo MA, Amantia D, Martinez-Martinez A, Clegg W, Harrington RW, Martinez VM, Houlton A. Reactions of Pd(II) with Chelate-Tethered 2,6-Diaminopurine Derivatives: N3-Coordination and Reaction of the Purine System. Inorganic Chemistry 2009, 48(23), 11085-11091.
• Galindo MA, Amantia D, Clegg W, Harrington RW, Eyre RJ, Goss JP, Briddon PR, McFarlane W, Houlton A. Self-assembly of a bis(adeninyl)-Cu(I) complex: a cationic nucleobase duplex mimic. Chemical Communications 2009, (20), 2833-2835.
• Izod K, Wills C, Clegg W, Harrington RW. Seven-Membered Cyclic Dialkylstannylene and -Plumbylene Compounds Stabilized by Agostic-type B-H center dot center dot center dot E Interactions [E = Sn, Pb]. Organometallics 2009,28 7 2211-2217.
• Izod K, Bowman LJ, Wills C, Clegg W, Harrington RW. Synthesis and structural characterisation of alkali metal complexes of heteroatom-stabilised 1,4-and 1,6-dicarbanions. Dalton Transactions 2009, (17), 3340-3347.
• Doherty S, Smyth CH, Harrington RW, Clegg W. Synthesis of Biaryl Diphosphines via a Stepwise Regioselective Double Diels-Alder Cycloaddition Elimination Sequence: Efficient Ligands for the Palladium-Catalyzed Amination of Aromatic Bromides. Organometallics 2009, 28(17), 5273-5276.
• Simonovic S, Whitwood AC, Clegg W, Harrington RW, Hursthouse MB, Male L, Douthwaite RE. Synthesis of Copper(I) Complexes of N-Heterocyclic Carbene-Phenoxyimine/amine Ligands: Structures of Mononuclear Copper(II), Mixed-Valence Copper(I)/(II), and Copper(II) Cluster Complexes. European Journal of Inorganic Chemistry 2009. PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY: WILEY-V C H VERLAG GMBH, (13), 1786-1795.
• Habibi M, Montazerozohori M, Lalegani A, Barati K, Harrington R, Clegg W. Synthesis, characterization and crystal structure of a CuSCN complex containing a new bidentate N,N′-bis(2-nitrocinnamaldehyde)ethylenediamine Schiff base and triphenylphosphine. Journal of Coordination Chemistry 2009, 62(22), 3703-3711.
• Burrows AD, Harrington RW, Kirk AS, Mahon MF, Marken F, Warren JE, Whittlesey MK. Synthesis, Characterization, and Electrochemistry of a Series of Iron(II) Complexes Containing Self-Assembled 1,5-Diaza-3,7-diphosphabicyclo[3.3.1]nonane Ligands. Inorganic Chemistry 2009, 48(20), 9924-9935.
• Barati K, Habibi MH, Montazerozohori M, Shafieyan H, Harrington RW, Clegg W. Synthesis, crystal structure and photo-induced isomerization of [N,N '-bis(4-fluorobenzylidene)ethylenediamine]bromo(triphenylphosphine)copper(I) complex. Journal of Coordination Chemistry 2009, 62(3), 417-426.
• Al-Karawi AJM, Clegg W, Harrington RW, Henderson RA. Synthetic, structural and kinetic studies on the binding of cyclohexane-1,2-bis(4-methyl-3-thiosemicarbazone) to divalent metal ions (Co, Ni, Cu, Zn or Cd). Dalton Transactions 2009, (3), 564-570.
• Benniston AC, Copley G, Harriman A, Rewinska DB, Harrington RW, Clegg W. A donor-acceptor molecular dyad showing multiple electronic energy-transfer processes in crystalline and amorphous states. Journal of the American Chemical Society 2008, 130(23), 7174-7175.
• Izod K, McFarlane W, Wills C, Clegg W, Harrington RW. Agostic-type B - H⋯Pb interactions stabilize a dialkylplumbylene. Structure of and bonding in [{nPr2P(BH3)}(Me 3Si)C(CH2)]2Pb. Organometallics 2008, 27(17), 4386-4394.
• Izod K, Stewart JC, Clegg W, Harrington RW. Alkali metal complexes of a naphthylamine-substituted phosphanide. Dalton Transactions 2008, (3), 363-370.
• Berry DJ, Seaton CC, Clegg W, Harrington RW, Coles SJ, Horton PN, Hursthouse MB, Storey R, Jones W, Friscic T, Blagden N. Applying hot-stage microscopy to co-crystal screening: A study of nicotinamide with seven active pharmaceutical ingredients. Crystal Growth & Design 2008,8 5 1697-1712.
• Doherty S, Knight JG, Smyth CH, Harrington RW, Clegg W. Biaryl-like CATPHOS diphosphines via double diels-alder cycloaddition between 1,4-bis(diphenylphosphinoyl)buta-1,3-diyne and anthracenes: Efficient ligands for the palladium-catalyzed amination of aromatic bromides and α-arylation of ketones. Organometallics 2008, 27(8), 1679-1682.
• Sbircea L, Sharma ND, Clegg W, Harrington RW, Horton PN, Hursthouse MB, Apperley DC, Boyd DR, James SL. Chemoenzymatic synthesis of chiral 4,4 '-bipyridyls and their metal-organic frameworks. Chemical Communications 2008, (43), 5538-5540.
• Habibi M, Barati K, Habibabadi H, Harrington R, Clegg W. Crystal structure of 3-(4-(dimethylamino)benzylidene)pentane-2,4-dione. Analytical Sciences: X-ray Structure Analysis Online 2008. ,24 12 x285-x286.
• Galindo MA, Houlton A, Clegg W, Harrington RW, Dobado J, Santoyo-Gonzalez F, Linares F, Romero MA, Navarro JAR. Electrochemically and photochemically active Palladium(II) heterotopic metallacalix[3]arenes. Chemical Communications 2008, (32), 3735-3737.
• Doherty S, Knight JG, Smyth CH, Harrington RW, Clegg W. Electron-Rich Bicyclic Biaryl-Like KITPHOS Monophosphines via [4+2] Cycloaddition Between 1-Alkynylphosphine Oxides and Anthracene: Highly Efficient Ligands for Palladium-Catalyzed C-N and C-C Bond Formation.. Advanced Synthesis & Catalysis 2008, 350(11-12), 1801-1806.
• Doherty S, Smyth CH, Harrington RW, Clegg W. Highly enantioselective synthesis of pseudo-C-2-symmetric axially chiral biaryl diphosphines via rhodium-catalyzed double [2+2+2] cycloaddition. Organometallics 2008, 27(19), 4837-4840.
• Belokon YN, Clegg W, Harrington RW, North M, Young C. In situ formation of heterobimetallic salen complexes containing titanium and/or vanadium ions. Inorganic Chemistry 2008, 47(9), 3801-3814.
• Fuller AM, Clegg W, Harrington RW, Hughes DL, Lancaster SJ. Mononuclear Ti N complexes formed by the facile multiple deprotonation of H3N center dot B(C6F5)(3): the importance of chloride ligands. Chemical Communications 2008, (44), 5776-5778.
• Skabara PJ, Pozo-Gonzalo C, Lardies Miazza N, Laguna M, Cerrada E, Luquin A, Gonzalez B, Coles SJ, Hursthouse MB, Harrington RW, Clegg W. Novel dithiolene complexes incorporating conjugated electroactive ligands. Dalton Transactions 2008, (23), 3070-3079.
• Ntirampebura D, Jagadish B, Nichol GS, Carducci MD, Dawson A, Rajapakshe A, Oliver AG, Clegg W, Harrington RW, Layne L, Margolis JI, Mash EA. Organic crystal engineering with 1,4-piperazine-2,5-diones. 7. Crystal packing of piperazinediones derived from 2-amino-7-nitro-4-methoxyindan-2-carboxylic acid. Crystal Growth & Design 2008, 8(9), 3257-3270.
• Doherty S, Knight JG, Mcrae A, Harrington RW, Clegg W. Oxazoline-substituted prolinamide-based organocatalysts for the direct intermolecular aldol reaction between cyclohexanone and aromatic aldehydes. European Journal of Organic Chemistry 2008, (10), 1759-1766.
• Benniston AC, Copley G, Elliott KJ, Harrington RW, Clegg W. Redox-controlled fluorescence modulation in a BODIPY-quinone dyad. European Journal of Organic Chemistry 2008, -(16), 2705-2713.
• Clegg W, Garcia-Alvarez J, Garcia-Alvarez P, Graham DV, Harrington RW, Hevia E, Kennedy AR, Mulvey RE, Russo L. Synthesis, structural authentication, and structurally defined metalation reactions of lithium and sodium DA-zincate bases (DA = diisopropylamide) with phenylacetylene. Organometallics 2008, 27(11), 2654-2663.
• Meghdadi S, Amirnasr M, Habibi MH, Amiri A, Ghodsi V, Rohani A, Harrington RW, Clegg W. Synthesis, structure, and electrochemistry of pyridinecarboxamide cobalt(III) complexes; the effect of bridge substituents on the redox properties. Polyhedron 2008, 27(13), 2771-2778.
• Armstrong DR, Clegg W, Dale SH, Garcia-Alvarez J, Harrington RW, Hevia E, Honeyman GW, Kennedy AR, Mulvey RE, O'Hara CT. Transamination chemistry of sodium TMP-zincate: Synthesis and crystal structure of a chiral amidozincate. Chemical Communications 2008, (2), 187-189.
• Blair VL, Carrella LM, Clegg W, Conway B, Harrington RW, Hogg LM, Klett J, Mulvey RE, Rentschler E, Russo L. Tuning the basicity of synergic bimetallic reagents: Switching the regioselectivity of the direct dimetalation of toluene from 2,5-to 3,5-positions. Angewandte Chemie 2008,47 33 6208-6211.
• Habibi MH, Zendehdel M, Barati K, Harrington RW, Clegg W. (E)-{4-Amino-3-[4-(dimethylamino)-benzylideneamino]phenyl}(phen-yl) -methanone. Acta Crystallographica Section E: Structure Reports Online 2007, 63(6), o2924.
• Habibi MH, Mokhtari R, Harrington RW, Clegg W. [N,N′-Bis(6-methoxysalicylidene)-1,3-diaminopropane]nickel(II). Acta Crystallographica Section E: Structure Reports Online 2007, 63(9), m2304.
• Habibi MH, Montazerozohori M, Lalegani A, Mokhtari R, Harrington RW, Clegg W. {N,N′-Bis[3-(2-nitro-phen-yl)prop-2-enyl-idene]ethyl-enediamine- κ2 N,N′}chlorido(triphenyl-phosphine-κP)copper(I). Acta Crystallographica Section E: Structure Reports Online 2007, 63(12), m2933-m2934.
• Habibi MH, Montazerozohori M, Mokhtari R, Harrington RW, Clegg W. 3,3′-Dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)] diphenol. Acta Crystallographica Section E: Structure Reports Online 2007, 63(11), o4462-.
• Habibi MH, Zendehdel M, Barati K, Harrington RW, Clegg W. A 1:1 cocrystal of 4-(dimethyl-amino)-benzaldehyde and 6-phenyl-1,3,5- triazine-2,4-diamine. Acta Crystallographica Section C: Crystal Structure Communications 2007, 63(8), 474-476.
• Benniston AC, Harriman A, Li P, Rostron JP, Harrington RW, Clegg W. A spectroscopic study of the reduction of geometrically restrained viologens. Chemistry - A European Journal 2007, 13(28), 7838-7851.
• Izod K, Wills C, Clegg W, Harrington RW. Alkali metal complexes of a phosphine-borane-stabilised carbanion: Influence of co-ligands on structure. Dalton Transactions 2007, (33), 3669-3675.
• Izod K, Stewart JC, Clegg W, Harrington RW. Alkali metal complexes of sterically demanding amino-functionalised secondary phosphanide ligands. Dalton Transactions 2007, (2), 257-264.
• Izod K, Wills C, Clegg W, Harrington RW. Alkaline earth metal complexes of a phosphine-borane-stabilized carbanion: Synthesis, structures, and stabilities. Inorganic Chemistry 2007, 46(10), 4320-4325.
• Belokon YN, Clegg W, Harrington RW, Young C, North M. Asymmetric cyanohydrin synthesis using heterobimetallic catalysts obtained from titanium and vanadium complexes of chiral and achiral salen ligands. Tetrahedron 2007, 63(24), 5287-5299.
• Doherty S, Knight JG, Bell AL, Harrington RW, Clegg W. Asymmetric hydrogenation of ketones with ruthenium complexes of rac- and enantiopure (S,S)-1,2-bis((diphenylphosphino)methyl)cyclohexane: A comparative study with rac- and (R)-BINAP. Organometallics 2007, 26(9), 2465-2468.
• Habibi MH, Mikhak M, Harrington RW, Clegg W. Bis[chloridobis(triphenyl-phosphine)-copper(I)-μ-chlorido]bis-(1, 2-diamino-propane)copper(II) acetonitrile disolvate. Acta Crystallographica Section E: Structure Reports Online 2007, 63(9), m2305-m2306.
• Habibi MH, Montazerozohori M, Barati K, Harrington RW, Clegg W. Bis[N,N′-(2-chloro-benzyl-idene)-ethylene-diamine-κ2 N,N′]copper(I) dichlorido-cuprate(I) acetonitrile solvate. Acta Crystallographica Section C: Crystal Structure Communications 2007, 63(12), m592-m594.
• Habibi M, Montazerozohori M, Barati K, Harrington R, Clegg W, Choi J. Crystal structure of N,N′-Bis(2-chlorobenzylidene)ethylenediamine. Analytical Sciences: X-ray Structure Analysis Online 2007. ,23 7 x117-x118.
• Habibi M, Barati K, Zendehdel M, Harrington R, Clegg W. Crystal structure of N,N′-bis(3-nitrobenzylidene)butane-1,4-diamine. Analytical Sciences: X-ray Structure Analysis Online 2007. ,23 4 x61-x62.
• Habibi MH, Montazerozohori M, Barati K, Harrington RW, Clegg W. Crystal structure of N,N'-Bis(4-trifluoromethoxybenzylidene)ethylenediamine. Analytical Sciences: X-Ray Structure Analysis Online 2007,23 3 x47-x48.
• Habibi MH, Sardashti MK, Barati K, Harrington RW, Clegg W. Crystal structures of new schiff bases N,N'-bis(2-hydroxy-3-methoxybenzyl- idene)-1,4-diaminobutane and N,N'-Bis(2-hydroxy-4-methoxybenzylidene)-1,2- diaminoethane. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences 2007,62 4 621-624.
• Doherty S, Knight JG, Smyth CH, Harrington RW, Clegg W. Efficient asymmetric carbonyl-ene reactions catalyzed by platinum metal lewis acid complexes of conformationally flexible NUPHOS diphosphines: A comparison with BINAP. Organometallics 2007, 26(25), 6453-6461.
• Berridge R, Wright SP, Skabara PJ, Dyer A, Steckler T, Argun AA, Reynolds JR, Harrington RW, Clegg W. Electrochromic properties of a fast switching, dual colour polythiophene bearing non-planar dithiinoquinoxaline units. Journal of Materials Chemistry 2007, 17(3), 225-231.
• Belokon' YN, Clegg W, Harrington RW, Ishibashi E, Nomura H, North M. Enantioselective and diastereoselective syntheses of cyanohydrin carbonates. Tetrahedron 2007, 63(39), 9724-9740.
• Izod K, Wills C, Clegg W, Harrington RW. Influence of aromatic ring substituents and co-ligand on the binding mode of a phosphine-borane-stabilized carbanion; crystal structures of [[(Me3Si)2{Ph2P(BH3)}C]KLn]2[Ln = (OEt2)2, pmdeta; pmdeta = N,N,N′,N″,N″-pentamethyldiethylenetriamine]. Journal of Organometallic Chemistry 2007, 692(22), 5060-5064.
• Izod K, Wills C, Clegg W, Harrington RW. Metalation of trimethylphosphine-borane. Unexpected reactivity of a simple phosphine-borane-stabilized carbanion toward siloxanes. Organometallics 2007, 26(11), 2861-2866.
• Doherty S, Knight JG, Smyth CH, Harrington RW, Clegg W. Metal-dependent reactivity of electrophilic platinum group metal lewis acid catalysts: Competitive alkene dimerization, intramolecular friedel-crafts alkylation, and carbonyl-ene reactivity. Organometallics 2007, 26(24), 5961-5966.
• Martin L, Day P, Akutsu H, Yamada J-I, Nakatsuji S, Clegg W, Harrington RW, Horton PN, Hursthouse MB, McMillan P, Firth S. Metallic molecular crystals containing chiral or racemic guest molecules. CrystEngComm 2007, 9(10), 865-867.
• Broomfield LM, Sarazin Y, Wright JA, Hughes DL, Clegg W, Harrington RW, Bochmann M. Mixed-ligand iminopyrrolato-salicylaldiminato group 4 metal complexes: Optimising catalyst structure for ethylene/propylene copolymerisations. Journal of Organometallic Chemistry 2007, 692(21), 4603-4611.
• Martin L, Day P, Clegg W, Harrington RW, Horton PN, Bingham A, Hursthouse MB, McMillan P, Firth S. Multi-layered molecular charge-transfer salts containing alkali metal ions. Journal of Materials Chemistry 2007, 17(31), 3324-3329.
• Habibi M, Montazerozohori M, Lalegani A, Harrington R, Clegg W. N,N′-Bis(2-nitrocinnamaldehyde)ethylenediaminedicholorozinc(II). Analytical Sciences: X-ray Structure Analysis Online 2007. ,23 3 x51-x52.
• Habibi MH, Mokhtari R, Harrington RW, Clegg W. N,N′-Bis(6-methoxysalicylidene)-1,3-diaminopropane]copper(II). Acta Crystallographica Section E: Structure Reports Online 2007, 63(7), m1998.
• Errington RJ, Petkar SS, Middleton PS, McFarlane W, Clegg W, Coxall RA, Harrington RW. Non-aqueous synthetic methodology for TiW5 polyoxometalates: Protonolysis of [(MeO)TiW5O18]3- with alcohols, water and phenols. Dalton Transactions 2007, (44), 5211-5222.
• Loghmani-Khouzani H, Sadeghi MM, Habibi MH, Harrington RW, Clegg W, Ghorbani MH. Novel 1:1 cocrystal of Benzoic acid and 2-(benzothiazol-2-yl)-1-phenylethenyl benzoate. Analytical Sciences. X-ray Structure Analysis Online 2007,23 3 x41-x42.
• Barbeau OR, Cano-Soumillac C, Griffin RJ, Hardcastle IR, Smith GCM, Richardson C, Clegg W, Harrington RW, Golding BT. Quinolinone and pyridopyrimidinone inhibitors of DNA-dependent protein kinase. Organic & Biomolecular Chemistry 2007, 5(16), 2670-2677.
• Doherty S, Knight JG, Smyth CH, Harrington RW, Clegg W. Rhodium-catalyzed double [2 + 2 + 2] cycloaddition of 1,4- bis(diphenylphosphinoyl)buta-1,3-diyne with tethered diynes: A modular, highly versatile single-pot synthesis of NU-BIPHEP biaryl diphosphines. Organic Letters 2007. , 9(23), 4925-4928.
• Lydon DP, Li P, Benniston AC, McFarlane W, Harrington RW, Clegg W. Solid phase and solution phase structural characterization of pyrene-based, T-shaped molecular dyads. European Journal of Organic Chemistry 2007, (10), 1653-1658.
• Clegg W, Dale SH, Graham DV, Harrington RW, Hevia E, Hogg LM, Kennedy AR, Mulvey RE. Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: Connections to ring-stacking, ring-laddering, and inverse crown concepts. Chemical Communications 2007,16 1641-1643.
• Marchetti F, Sayle KL, Bentley J, Clegg W, Curtin NJ, Endicott JA, Golding BT, Griffin RJ, Haggerty K, Harrington RW, Mesguiche V, Newell DR, Noble MEM, Parsons RJ, Pratt DJ, Wang L, Hardcastle IR, Mesguiche V, Newell DR, Noble MEM, Parsons RJ, Pratt DJ, Wang L, Hardcastle IR. Structure-based design of 2-arylamino-4-cyclohexylmethoxy-5-nitroso-6- aminopyrimidine inhibitors of cyclin-dependent kinase 2. Organic and Biomolecular Chemistry 2007, 5(10), 1577-1585.
• Habibi M, Montazerozohori M, Lalegani A, Harrington R, Clegg W. Synthesis and crystal Structure of [CuL(PPh3)Cl] L = N,N′-bis(4-trifluromethylbenzylidene)ethylenediamine. Analytical Sciences: X-ray Structure Analysis Online 2007. ,23 3 x49-x50.
• Habibi MH, Montazerozohori M, Barati K, Harrington RW, Clegg W. Synthesis and crystal structure of chloro{bis[N,N'-(2-chlorobenzylidene)]ethylenediamine}(triphenylphosphine)copper(I). Analytical Sciences. X-ray Structure Analysis Online 2007,23 3 x45-x46.
• Errington RJ, Petkar SS, Middleton PS, McFarlane W, Clegg W, Coxall RA, Harrington RW. Synthesis and reactivity of the methoxozirconium pentatungstate ( nBu4N)6[{(μ-MeO)ZrW5O 18}2]: Insights into proton-transfer reactions, solution dynamics, and assembly of {ZrW5O18}2- building blocks. Journal of the American Chemical Society 2007,129 40 12181-12196.
• Ronson TK, Adams H, Harding LP, Harrington RW, Clegg W, Ward MD. Synthesis and structures of cadmium(II) complexes of a series of multinucleating N/S donor ligands. Polyhedron 2007, 26(12), 2777-2785.
• Bowman LJ, Izod K, Clegg W, Harrington RW. Synthesis and structures of Ln(II) and Ln(III) dialkyls derived from LnI2 (Ln = Nd, Tm, Yb). Organometallics 2007,26 10 2646-2651.
• Clegg W, Harrington RW. Tetrakis(1,10-phenanthrolinium) hexa-chloridoeuropate(III) chloride. Acta Crystallographica Section E: Structure Reports Online 2007,63 4 m1152.
• Habibi MH, Mokhtari R, Harrington RW, Clegg W. The Schiff base N,N′-bis-(3-nitrobenzylidene)propane-1,3-diamine. Acta Crystallographica Section E: Structure Reports Online 2007,63 6 o2881.
• Mountford AJ, Clegg W, Coles SJ, Harrington RW, Horton PN, Humphrey SM, Hursthouse MB, Wright JA, Lancaster SJ. The synthesis, structure and reactivity of B (C6F 5)3-stabilised amide (M-NH2) complexes of the Group 4 metals. Chemistry: A European Journal 2007, 13(16), 4535-4547.
• Guille K, Harrington RW, Clegg W. Violuric acid monohydrate: a second polymorph with more extensive hydrogen bonding. Acta Crystallographica Section C: Crystal Structure Communications 2007,63 6 o327-o329.
• Bowman LJ, Izod K, Clegg W, Harrington RW. σ-Bonded organometallic derivatives of yttrium(III) and thulium(III): An unusual ligand coupling reaction mediated by thulium(III). Journal of Organometallic Chemistry 2007, 692(4), 806-812.
• Plater MJ, Kemp S, Coronado E, Gomez-Garcia CJ, Harrington RW, Clegg W. A stable oxoverdazyl free radical: Structural and magnetic characterization. Polyhedron 2006,25 12 2433-2438.
• Choi J-H, Clegg W, Harrington RW, Yoon H-M, Hong YP. A tetraazamacrocycle with benzyl substituents. Acta Crystallographica Section E: Structure Reports Online 2006,62 2 o644-o646.
• Bowman LJ, Izod K, Clegg W, Harrington RW, Smith JD, Eaborn C. Alkali metal complexes of sterically hindered mono- and di-carbanions containing Si-O bonds. Dalton Transactions 2006,3 502-508.
• Izod K, Liddle ST, Clegg W, Harrington RW. Amino-functionalised diarylphosphide complexes of the alkali metals and lanthanum. Dalton Transactions 2006,28 3431-3437.
• Lin P, Clegg W, Harrington RW, Henderson RA, Fletcher AJ, Bell J, Thomas KM. Assembly of heterometallic clusters and coordination polymers by combining Mo-S-based clusters with Mn²⁺. Inorganic Chemistry 2006, 45(10), 4284-4302.
• Doherty S, Knight JG, Smyth CH, Harrington RW, Clegg W. Asymmetric platinum group metal-catalyzed carbonyl-ene reactions: Carbon-carbon bond formation versus isomerization. Journal of Organic Chemistry 2006, 71(26), 9751-9764.
• Kays DL, Day JK, Aldridge S, Harrington RW, Clegg W. Cationic terminal borylene complexes: Interconversion of amino and alkoxy borylenes by an unprecedented Meerwein-Ponndorf hydride transfer. Angewandte Chemie International Edition 2006, 45(21), 3513-3516.
• Argent SP, Adams H, Riis-Johannessen T, Jeffery JC, Harding LP, Clegg W, Harrington RW, Ward MD. Complexes of Ag(i), Hg(i) and Hg(ii) with multidentate pyrazolyl-pyridine ligands: From mononuclear complexes to coordination polymers via helicates, a mesocate, a cage and a catenate. Dalton Transactions 2006, (42), 4996-5013.
• Izod K, Wills C, Clegg W, Harrington RW. Heavier alkali metal complexes of a silicon- and phosphine-borane- stabilized carbanion. Organometallics 2006,25 22 5326-5332.
• Bowman LJ, Izod K, Clegg W, Harrington RW. Heteroleptic complexes of lanthanum(III) and neodymium(III) with oxygen- or nitrogen-functionalized tris(triorganosilyl)methyl ligands. Organometallics 2006, 25(12), 2999-3006.
• Berridge R, Skabara PJ, Pozo-Gonzalo C, Kanibolotsky A, Lohr J, McDouall JJW, McInnes EJL, Wolowska J, Winder C, Sariciftci NS, Harrington RW, Clegg W. Incorporation of fused tetrathiafulvalenes (TTFs) into polythiophene architectures: Varying the electroactive dominance of the TTF species in hybrid systems. Journal of Physical Chemistry B 2006, 110(7), 3140-3152.
• Ronson TK, Lazarides T, Adams H, Pope SJA, Sykes D, Faulkner S, Coles SJ, Hursthouse MB, Clegg W, Harrington RW, Ward MD. Luminescent PtII(bipyridyl)(diacetylide) chromophores with pendant binding sites as energy donors for sensitised near-infrared emission from lanthanides: Structures and photophysics of PtII/Ln III assemblies. Chemistry: A European Journal 2006, 12(36), 9299-9313.
• Aldridge S, Kays DL, Al-Fawaz A, Jones KM, Horton PN, Hursthouse MB, Harrington RW, Clegg W. Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment. Chemical Communications 2006,24 2578-2580.
• Doherty S, Knight JG, Smyth CH, Sore NT, Rath RK, McFarlane W, Harrington RW, Clegg W. Modular synthesis of a new class of bis(amino-oxazoline) using palladium-catalyzed Buchwald-Hartwig amination methodology. Organometallics 2006, 25(18), 4341-4350.
• Clegg W, Dale SH, Harrington RW, Hevla E, Honeyman GW, Mulvey RE. Post-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide. Angewandte Chemie International Edition 2006, 45(15), 2374-2377.
• Loghmani-Khouzani H, Osmailowski B, Gawinecki R, Kolehmainen E, Harrington RW, Clegg W. Preparation, reactivity and tautomeric preferences of novel (1H-quinolin-2-ylidene)propan-2-ones. Journal of the Iranian Chemical Society 2006, 3(2), 173-179.
• Izod K, McFarlane W, Tyson BV, Carr I, Clegg W, Harrington RW. Stabilization of a dialkylstannylene by unusual B-H⋯Sn γ-agostic-type interactions. A structural, spectroscopic, and DFT study. Organometallics 2006, 25(5), 1135-1143.
• Habibi MH, Loghmani-Khouzani H, Sadeghi MM, Harrington RW, Clegg W, Ghorbani MH. Synthesis and crystal structure of 1,1-dimethoxy-4-phenylamino-4-methylthio-3-buten-2-one. Analytical Sciences: X-Ray Structure Analysis Online 2006,22 12 x283-x284.
• Llarena I, Benniston AC, Izzet G, Rewinska DB, Harrington RW, Clegg W. Synthesis of a redox-active molecular switch based on dibenzo[1,2]dithiine. Tetrahedron Letters 2006,47 51 9135-9138.
• Izod K, Wills C, Clegg W, Harrington RW. Synthesis, crystal structure, and solution behavior of a sterically hindered α-metalated phosphine-borane. Organometallics 2006,25 1 38-40.
• Habibi MH, Montazerozohori M, Lalegani A, Harrington RW, Clegg W. Synthesis, structural and spectroscopic properties of a new Schiff base ligand N,N′-bis(trifluoromethylbenzylidene)ethylenediamine. Journal of Fluorine Chemistry 2006, 127(6), 769-773.
• Pennington DA, Harrington RW, Clegg W, Bochmann M, Lancaster SJ. The synthesis, structure and ethene polymerization activity of octahedral heteroligated (salicylaldiminato)(β-enaminoketonato)titanium complexes: The X-ray crystal structure of {3-But-2-(O)C6H3CHN(Ph)}{(Ph)NC(Me)C(H)C(Me)O}TiCl2. Journal of Organometallic Chemistry 2006, 691(14), 3183-3188.
• Koroglu A, Bulut A, Ucar I, Nichol GS, Harrington RW, Clegg W. A second monoclinic polymorph of 2,9-dimethyl-1,10-phenanthroline dihydrate. Acta Crystallographica Section E: Structure Reports Online 2005, 61(11), o3723-o3725.
• Koeroglu A, Bulut A, Ucar I, Nichol GS, Harrington RW, Clegg W. A second monoclinic polymorph of 2,9-dimethyl-1,10-phenanthroline dihydrate. Acta Crystallographica, Section E: Structure Reports Online 2005,E61 11 o3723-o3725.
• Izod K, McFarlane W, Allen B, Clegg W, Harrington RW. An intramolecularly base-stabilized diphosphagermylene and two unusual germanium(II) ate complexes: A structural, NMR, and DFT study. Organometallics 2005, 24(9), 2157-2167.
• Burrows AD, Harrington RW, Mahon MF. Diaquabis(1,1,4-trimethylthiosemicarbazide)-nickel(II) dinitrate. Acta Crystallographica Section E: Structure Reports Online 2005,61 3 m551-m553.
• Izod K, Young J, Clegg W, Harrington RW. Effect of peripheral donor substituents on the binding modes of phosphinomethanide ligands. Synthesis and crystal structures of alkali metal derivatives of an O-functionalised phosphinomethanide ligand. Dalton Transactions 2005,9 1658-1663.
• Mountford AJ, Clegg W, Harrington RW, Humphrey SM, Lancaster SJ. New titanium and zirconium complexes with M-NH2 bonds formed by facile deprotonation of H3N·B(C6F5) 3. Chemical Communications 2005,15 2044-2046.
• Koroglu A, Bulut A, Ucar I, Nichol GS, Harrington RW, Clegg W. Proton sharing in bis(4-carbamoyl-pyridinium) squarate. Acta Crystallographica Section C: Crystal Structure Communications 2005,61 12 o678-o680.
• Doherty S, Knight JG, Rath RK, Clegg W, Harrington RW, Newman CR, Campbell R, Amin H. Ruthenium complexes of six-electron-donor NUPHOS-Type diphosphines: Highly selective catalysts for the hydrocarboxylation of terminal alkynes. Organometallics 2005, 24(11), 2633-2644.
• Lin P, Clegg W, Harrington RW, Henderson RA. Synthesis and characterization of a Mo/Ag/Rb heterotrimetallic cluster with double-cage architecture. Dalton Transactions 2005,14 2349-2351.
• Lin P, Clegg W, Harrington RW, Henderson RA. Synthesis and structures of 5-(pyridyl)tetrazole complexes of Mn(II). Dalton Transactions 2005,14 2388-2394.
• Autissier V, Brockman E, Clegg W, Harrington RW, Henderson RA. Synthesis of [Ni(η2-CH2C6H 4R-4){PPh(CH2CH2PPh2) 2}]+ (R = H, Me or MeO) and protonation reactions with HCl. Journal of Organometallic Chemistry 2005,690 7 1763-1771.
• Burrows AD, Harrington RW, Mahon MF, Teat SJ. The structural influence of ligand coordination and hydrogen bonding capabilities in the crystal engineering of metal thiosemicarbazide compounds with malonate. CrystEngComm 2005, 7, 388-397.
• Pennington DA, Clegg W, Coles SJ, Harrington RW, Hursthouse MB, Hughes DL, Light ME, Schormann M, Bochmann M, Lancaster SJ. The synthesis, structure and ethene polymerisation catalysis of mono(salicylaldimmato) titanium and zirconium complexes. Dalton Transactions 2005,3 561-571.
• Clegg W, Golding BT, Harrington RW, Scott R. 1-{2-[4-(2,4-Dinitrophenyl)piperazin-1 -yl]ethyl}-4-aza-1-azoniabicyclo[2. 2.2]octane chloride. Acta Crystallographica Section E: Structure Reports Online 2004,60 2 o291-o293.
• Benniston AC, Clegg W, Harrington RW, Li P. A sterically constrained bis(2,2′:6′,2″-terpyridine) ligand. Acta Crystallographica Section E: Structure Reports Online 2004,60 12 o2452-o2454.
• Burrows AD, Donovan AS, Harrington RW, Mahon MF. Backbone flexibility and counterion effects on the structure and thermal properties of Di(thiourea)zinc dicarboxylate coordination polymers. European Journal Of Inorganic Chemistry 2004,23 4686-4695.
• Izod K, McFarlane W, Tyson BV, Clegg W, Harrington RW. Complexes of a dianionic bis(diphosphinomethanide) with lithium, sodium, potassium and zirconium. Effect of substitution on the Schlenk dimerisation of vinylidene phosphines. Dalton Transactions 2004,23 4074-4078.
• Bell NA, Clegg W, Coles SJ, Constable CP, Harrington RW, Hursthouse MB, Light ME, Raper ES, Sammon C, Walker MR. Complexes of heterocyclic thiones and group 12 metals: Part VI. Preparation and characterisation of complexes of cadmium(II) halides with 1-methylimidazoline-2(3H)-thione, 1,3-thiazolidine-2-thione and 1,3-benzothiazoline-2-thione. Crystal structures of polymeric (1,3-thiazolidine-2-thione)cadmium(II) chloride, bis(1,3-thiazolidine-2-thione) cadmium(II) iodide. Inorganica Chimica Acta 2004,357 7 2091-2099.
• Blair S, Izod K, Clegg W, Harrington RW. Complexes of the heavier alkaline earth metals Ca, Sr, and Ba with O-functionalized phosphanide ligands. Inorganic Chemistry 2004,43 26 8526-8531.
• Burrows AD, Harrington RW, Mahon MF. Dichlorobis(1,3-dimethylthiourea-kS)zinc(II). Acta Crystallographica, Section E: Structure Reports Online 2004,E60 9 m1317-m1318.
• Burrows AD, Harrington RW, Mahon MF, Teat SJ. Manipulation of molecular and supramolecular structure in nickel(II) complexes through the orientation of dicarboxylate hydrogen bonding faces. Crystal Growth & Design 2004,4 4 813-822.
• Lin P, Henderson RA, Harrington RW, Clegg W, Wu C-D, Wu X-T. New 1- and 2-Dimensional Polymeric Structures of Cyanopyridine Complexes of Ag1 and Cu1. Inorganic Chemistry 2004,43 1 181-188.
• Autissler V, Clegg W, Harrington RW, Henderson RA. Proton Transfer to Nickel-Thiolate Complexes. 1. Protonation of [Ni(SC 6H4R-4)2(Ph2PCH2CH 2PPh2)] (R = Me, MeO, H, Cl, or NO2). Inorganic Chemistry 2004,43 10 3098-3105.
• Autissier V, Zarza PM, Petrou A, Henderson RA, Harrington RW, Clegg W. Proton Transfer to Nickel-Thiolate Complexes. 2. Rate-Limiting Intramolecular Proton Transfer in the Reactions of [Ni(SC6H 4R-4)(PhP{CH2CH2PPh2} 2)]+ (R = NO2, Cl, H, Me, or MeO). Inorganic Chemistry 2004,43 10 3106-3115.
• Onions ST, Heath SL, Price DJ, Harrington RW, Clegg W, Matthews CJ. Self-assembly of a spin-coupled octanuclear copper(II) circular array from a single-stranded ligand. Angewandte Chemie, International Edition 2004,43 14 1814-1817.
• Izod K, McFarlane W, Tyson BV, Clegg W, Harrington RW. Synthesis and structural characterisation of a novel phosphine-borane- stabilised dicarbanion and an unusual bis(phosphine-borane). Chemical Communications 2004,10 5 570-571.
• Izod K, McFarlane W, Tyson BV, Clegg W, Harrington RW, Liddle ST. Alkali Metal-Mediated Schlenk Dimerization of a Phosphorus-Substituted Alkene. Synthesis and Crystal Structures of Li, Na, and K Derivatives of a Phosphorus-Stabilized Butane-l,4-diide Ligand. Organometallics 2003,22 18 3684-3690.
• Blair S, Izod K, Clegg W, Harrington RW. Organomagnesium phosphanide "grignard" analogues - Synthesis, structural characterisation and solution behaviour of [BuMg{P(CH[SiMe 3]2)(C6H3-2-OMe-3R)}]2 [R = H, Me]. European Journal of Inorganic Chemistry 2003,18 3319-3324.
• Darley DJ, Selmer T, Clegg W, Harrington RW, Buckel W, Golding BT. Stereocontrolled Synthesis of (2R,3S)-2-Methylisocitrate, a Central Intermediate in the Methylcitrate Cycle. Helvetica Chimica Acta 2003,86 12 3991-3999.
• Blair S, Izod K, Harrington RW, Clegg W. Sterically controlled mono- or dimetalation of a thioether-functionalized phosphine and an unusual light-induced phosphide-thiolate rearrangement. Organometallics 2003,22 2 302-308.
• Burrows AD, Harrington RW, Mahon MF, Teat SJ. Structural manipulation of hydrogen bond networks using sulfonated phosphane ligands and their complexes: Competition and interplay between strong and weak hydrogen bonds. European Journal Of Inorganic Chemistry 2003,7 1433-1439.
• Burrows AD, Harrington RW, Mahon MF, Palmer MT, Senia F, Varrone M. Synthesis and reactivity of rhodium(I) complexes containing keto-functionalised N-pyrrolyl phosphine ligands. Dalton Transactions 2003,19 3717-3726.
• Benniston AC, Clegg W, Harriman A, Harrington RW, Li P, Sams C. Synthesis of a biphenyl-based cyclophane via benzidine rearrangement of a constrained m-nitrophenol derivative. Tetrahedron Letters 2003,44 13 2665-2667.
• Burrows AD, Harrington RW, Mahon MF, Teat SJ. The influence of functional group orientation on the structure of zinc 1,1,4-trimethylthiosemicarbazide dicarboxylates: Probing the limits of crystal engineering strategies. European Journal Of Inorganic Chemistry 2003,4 766-776.
• Burke NJ, Burrows AD, Donovan AS, Harrington RW, Mahon MF, Price CE. Zinc dicarboxylate polymers and dimers: thiourea substitution as a tool in supramolecular synthesis. Dalton Transactions 2003,20 3840-3849.
• Babb JEV, Burrows AD, Harrington RW, Mahon MF. Zinc thiosemicarbazide dicarboxylates: the influence of the anion shape on supramolecular structure. Polyhedron 2003,22 5 673-686.
• Clegg W, Harrington RW. (11SR,15SR)-9,10,11,15-Tetrahydro-9-[(1SR)-1-methoxyethyl]-9,10-[3 ',4 ']furanoanthracene-12,14-dione. Acta Crystallographica Section E: Structure Reports Online 2002,58 12 O1411-O1412.
• Clegg W, Harrington RW. (3aSR,9aSR)-3a,4,9,9a-Tetrahydro-4-[(1SR)-1-methoxyethyl]-2-methyl-4,9-[1',2']benzeno-1H-benzo[f]isoindole-1,3-(2H)-dione. Acta Crystallographica, Section E: Structure Reports Online 2002,E58 12 o1413-o1414.
• Burrows AD, Harrington RW, Mahon MF. Hydrogen bond directed crystal engineering of nickel complexes: the crystal structure of cis-bis(4-ethylthiosemicarbazide)nickel(II) terephthalate and the influence of metal geometry on supramolecular structure. CrystEngComm 2002,2 77-81.
• Burrows AD, Harrington RW, Mahon MF, Teat SJ. Structural manipulation through selective substitution of hydrogen bonding groups: the supramolecular structures of bis(thiosemicarbazidato)nickel complexes. CrystEngComm 2002,4 89 539-544.
• Goodyear JW, Hemingway CW, Harrington RW, Wisemann MR, Brisdon BJ. The crystal structure of [Mo(NCS)(CO)2(η3-C3H5) (NCMe)2].MeCN and the reactions of {Mo(CO)2 (η3-C3H5)+} containing species with symmetric alkynes. Journal of Organometallic Chemistry 2002. ,664 1-2 176-181.
• Burrows AD, Harrington RW, Mahon MF, Price CE. The influence of hydrogen bonding on the structure of zinc co-ordination polymers. Dalton Transactions 2000,21 3845-3854.
• Burrows AD, Harrington RW, Mahon MF. 2,2 '-Bipyridine-5-sulfonic acid. Acta Crystallographica, Section C: Crystal Structure Communications 1999,55 11 1921-1923.