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New self-forming membrane to protect our environment

New self-forming membrane to protect our environment

1 May 2020

A new class of self-forming membrane to separate carbon dioxide from a mixture of gases has been developed by Newcastle University researchers.

Operating like a coffee filter, it lets harmless gases, such as nitrogen, exit into the atmosphere and then the carbon dioxide can be processed.

The team believe that the system may be applicable for use in carbon dioxide separation processes, either to protect the environment or in reaction engineering.

By growing the expensive part of the membrane - made from silver - during membrane operation, they dramatically reduced the demand for silver and the cost of the membrane.

The work is published in Energy and Environmental Science. Dr Greg Mutch, NUAcT Fellow from the School of Engineering, Newcastle University, UK explains, “We didn’t build the entire membrane from silver, instead we added a small amount of silver and grew it within the membrane adding the functionality we desired.

“Most importantly, the performance of the membrane is at the level required to be competitive with existing carbon capture processes – in fact, it would likely reduce the size of the equipment required significantly and potentially lower operating costs.”

What is carbon capture and why is it needed?

Carbon dioxide emissions are the main driver of climate change. Currently, our climate is approximately 1°C warmer than pre-industrial times. We have already emitted enough carbon dioxide to warm the planet beyond 1.5°C (there is a lag between emissions and warming), and we have international agreements in place to ensure that we do not pass 2°C.

Warming beyond 2°C will have disastrous consequences, including impacts on human health, food availability, large-scale migration and our environment. We urgently need new materials and processes that reduce the amount of carbon dioxide we emit to the atmosphere – these technologies are referred to as carbon capture and storage (CCS).

Although we are making big efforts with renewable energy and electric vehicles, the world is still predominantly powered by fossil fuels and we are very unlikely to be able to reduce that contribution in time to limit warming to less than 2°C.

In addition, large modelling exercises such as by the Intergovernmental Panel on Climate Change, have repeatedly shown that the most cost-effective way to slow global warming always involves a significant amount of CCS (in the mix with eg renewable energy technologies).

The self-forming membrane

In a method never tried before and described in the research paper, aluminium oxide supports in pellet and tubular form were used to grow the silver membrane. Silver was added to the membrane, and the conditions experienced during operation forced the silver to grow within the membrane, bestowing higher performance.

Using X-ray micro-computed tomography, the team were able to look inside the membrane and confirm that the permeation of CO2 and O2 stimulated self-assembly of silver dendrites.

Importantly, the performance of the membrane was shown through permeation measurements to be at the level required to be competitive with existing carbon capture processes. The permeability of the membrane was one order of magnitude higher than that required, and the flux of CO2 was the highest reported for this class of membrane.

Dr Mutch added: “These savings are important – the cost of carbon capture is one of the key factors limiting uptake of the technology. There is a common metric for membrane performance – the “upper bound”. As our membrane relies on a unique transport mechanism, we avoid the limitations of most membrane materials and go far beyond the upper bound!

“We hope that this study inspires new ways to form membranes, that lower costs, as well as drives interest in this new class of membrane for future application to protect our environment.”

Reference: Dendritic silver self-assembly in molten-carbonate membranes for efficient carbon dioxide capture. Liam  A. McNeil,   Greg A. Mutch,  Francesco  Iacoviello,  Josh  J. Bailey,  Georgios Triantafyllou, Dragos Neagu,  Thomas S. Miller,  Evangelos I. Papaioannou,  Wenting Hu,  Dan J.L. Brett,  Paul R. Shearing  and Ian S. Metcalfe. Energy and Environmental Science. Doi: 10.1039/c9ee03497h